Product ID:FUMARIC ACID,22044-0050
MSDS Date:07/16/1996
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKJJM

Emergency Phone: 800-424-9300

Info Phone: 800-227-6701

Cage: ACR0S

Telephone: 800-227-6701

Cage: ACR0S

(ORAL,RAT) 9300 MG/KG.

CAS: 110-17-8

RTECS: LS9625000

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENT.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES IRRITATION. SKIN:
MAY CAUSE IRRITATION. INGESTION: THE TOXICOLOGICAL PROPERTIES OF
THIS SUBSTANCE HAVE NOT BEEN FULLY INVESTIGATED. INHALATION: MAY
CAUSE RESPIRATORY TRACT IRRITATIO N. THE TOXICOLOGICAL PROPERTIES
OF THIS SUBSTANCE HAVE NOT BEEN THOROUGHLY INVESTIGATED. CHRONIC:
NOT AVAILABLE.
Explanation of Carcinogenicity:FUMARIC ACID - NOT LISTED BY ACGIH,
IARC, NIOSH, NTP OR OSHA.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES,
OCCASIONALLY LIFTING UPPER AND LOWER LIDS. GET MEDICAL AID. SKIN:
GET MEDICAL AID. FLUSH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
INGESTION: GET MEDICAL AID. WASH OUT MOUTH WITH WATER. INHALATION:
REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING,
GIVE ARTIFICIAL RESP IRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. GET MEDICAL AID. NOTES TO MD: TREAT SYMPTOMATICALLY AND
SUPPORTIVELY.

Flash Point:=230.C, 446.F
Autoignition Temp:=375.C, 707.F
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:IN CASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL
FOAM, OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NFPA RATING: NOT PUBLISHED.

Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. SWEEP
UP, THEN PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL.

Handling and Storage Precautions:AVOID BREATHING DUST, VAPOR, MIST OR
GAS. AVOID CONTACT WITH SKIN AND EYES. STORE IN A COOL, DRY PLACE.
STORE IN A TIGHTLY CLOSED CONTAINER.
Other Precautions:IRRITATING TO EYES.

Respiratory Protection:WEAR A NIOSH OR EUROPEAN STANDARD EN 149
APPROVED FULL-FACEPIECE AIRLINE RESPIRATOR IN THE POSITIVE PRESSURE
MODE WITH EMERGENCY ESCAPE PROVISIONS.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN
AND TO PREVENT SKIN EXPOSURE.
Supplemental Safety and Health
PHYSICAL AND CHEMICAL PROPERTIES: MOLECULAR FORMULA: HO2CCH=CHCO2H.
MOLECULAR WEIGHT: 116.07.

Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:>299.C, 570.2F
M.P/F.P Text:299C - 300C
Decomp Temp:>350.C, 662.F
Vapor Pres:1.7 MM HG @ 165C
Spec Gravity:1.6250 G/CM3
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Solubility in Water:0.63 G/100 ML @ 25C
Appearance and Odor:WHITE CRYSTALLINE POWDER; NO ODOR AVAILABLE.

Stability Indicator/Materials to Avoid:YES
NOT AVAILABLE.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.

Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS.

Toxicological Information:SEE ACTUAL ENTRY IN RTECS FOR COMPLETE
INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:FOR FURTHER INFORMATION, CONTACT ACROS ORGANICS.

Transport Information:U.S. DOT: SHIPPING NAME: NO INFORMATION
AVAILABLE. HAZARD CLASS; UN NUMBER; PACKING GROUP: N/P. --
I.M.O./I.A.T.A./R.I.D./A.D.R.: SHIPPING NAME; HAZARD CLASS; UN
NUMBER; PACKING GROUP: N/P. -- CANADIA N T.D.G.: SHIPPING NAME: NO
INFORMATION AVAILABLE. HAZARD CLASS; UN NUMBER; PACKING GROUP: N/P.

Federal Regulatory Information:EUROPEAN/INTERNATIONAL REGULATIONS:
EUROPEAN LABELING I/A/W EC DIRECTIVES: HAZARD SYMBOLS: XI. RISK
PHRASES: R 36 - IRRITATING TO EYES. SAFETY PHRASES: S 26 - IN CASE
OF CONTACT WITH EYES, RINSE IMMED IATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE. WGK (WATER DANGER/PROTECTION): CAS #110-17-8:
1. CANADA: CAS #110-17-8 IS LISTED ON CANADA'S DSL/NDSL LIST; CAS
#110-17-8 IS NOT LISTED ON CANADA'S INGREDIENT DISCLOSURE LIST.
EXPOSURE LIMITS: N/P. U.S. FEDERAL: TSCA: CAS #110-17-8 IS LISTED
ON TH E TSCA INVENTORY.